3.Supramolecular Organogel of Tetrafluoromethylaniline copper (II) nitrate Derivative and its Spectroscopic study.
Author's Name: Rooshan WatanpalAbstract—Electron-bearing alpha-cyanostyrene removing tetrafluoromethyl groups was produced. Due to the restriction of intramolecular rotations, the alpha-cyanostyrene skeleton supports accumulation improved emission behaviour. Remarkably, similar to its solution state, the cyanostyrenes possessing simple tetrafluoromethyl (CF3) substituents form stable organogels with improved fluorescence emission. In water, via intermolecular H- bonding, π-π stacking, and cyano substituent associations, the CF3 substituted self-assembles to an interconnected fibrous nano/microstructures. Using scanning electron microscopy (SEM), infrared microscopy, the morphological characteristics of the aggregates and the gels were substantiated studied, infrared spectroscopy shows multiple functional groups.